Glossary entry

English term or phrase:

Hydroxymethylpentylcyclohexencarboxyldehyd

English answer:

Hydroxymethylpentylcyclohexenecarboxaldehyde

Added to glossary by ysun
Sep 6, 2006 17:03
17 yrs ago
English term

Hydroxymethylpentylcyclohexencarboxyldehyd

English Science Chemistry; Chem Sci/Eng Cosmetics
Can anybody give me the proper spelling of this term? I think it should at least end in "...dehyde". It appears in a list of ingredients of a cosmetic product. The ingredients are given in English, but the packaging is produced in Germany. Now German chemical terms tend to be really long like this, but it seems doubtful to me in English. Also, I do not get a single hit on Google in any language.

Discussion

Nesrin Sep 6, 2006:
Commercial names: Lyral® and Kovanol®
Nesrin Sep 6, 2006:
Check this as well http://www.hermal.de/her_en/pages/trolab/trolab_database.php...
The reason you didn't find it on any English-language sites is that it appears to be "-carboxAl-" not "-carboxyl-" in English.
Marie-Hélène Hayles Sep 6, 2006:
here's another link (list of potential allergens in cosmetic products) with the same substance:
http://tinyurl.com/el897

Responses

+1
2 hrs
Selected

Hydroxymethylpentylcyclohexenecarboxaldehyde

Correct spelling should be Hydroxymethylpentylcyclohexenecarboxaldehyde.

See: Hydroxymethylpentylcyclohexenecarboxaldehyde
http://en.wikipedia.org/wiki/Hydroxymethylpentylcyclohexenec...

Carboxaldehyde refers to a chemical radical: -CH=O, i.e., a substituted formaldehyde.

Also see cyclohexane carboxaldehyde at: http://leonlab.bio.uci.edu/odorant.cfm?id=190


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Note added at 2 hrs (2006-09-06 20:01:30 GMT)
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Please put in some hyphens and search Hydroxy-methyl-pentyl-cyclohexen-carboxyldehyd on Google, and then enjoy the magic!

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Note added at 14 hrs (2006-09-07 07:53:56 GMT)
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"Carboxyldehyde" is definitely a typo. This compound has nothing to do with "carboxyl", which has the formula of -C(=O)-OH while carboxaldehyde has the formula of -CH=O. Please see definition of "carboxyl" at http://en.wikipedia.org/wiki/Carboxyl

Also, please see the structure of one of the isomers of hydroxymethylpentylcyclohexenecarboxaldehyde at http://www.iff.com/Ingredients.nsf/0/67B1B80D780230918025699...

By other means, if you search "carboxyldehyde" on Google, you will not get a single hit, but if you search "carboxaldehyde" on Google, you will get about 170,000 hits. If you search "hydroxymethylpentylcyclohexenecarboxaldehyde", you will get about 160 hits.


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Note added at 15 hrs (2006-09-07 08:16:11 GMT)
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Please also see this link: http://www.hermal.de/her_en/pages/trolab/trolab_database.php...


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Note added at 23 hrs (2006-09-07 16:25:30 GMT)
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Basically, hydroxymethylpentylcyclohexenecarboxaldehyde is an Aldehyde. It can be regarded as a derivative of cyclohexene carboxaldehyde. Cyclohexene has a 6-carbon atom ring and a double bond. There is no position 10 in its ring (6 is the maximum).

Here are the CAS registered names of this compound (CAS No. 31906-04-4):
4-(4-Hydroxy-4-methyl pentyl)-3-cyclohexene-1-carboxaldehyde
Synonyms: 3 and 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde; 4-(4-Hydroxy-4-methyl pentyl)-3-cyclohexene-1-carboxaldehyde; 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexenecarbaldehyde;
Peer comment(s):

agree Charlesp
6 hrs
Thanks, Charles!
Something went wrong...
4 KudoZ points awarded for this answer. Comment: "Thank you very much for the brainstorming; you have all been very helpful."
+4
14 mins

4-(4-hydroxy-4-methyl pentyl)-3-cyclohexene-10-carboxyldehyde

This is given in a paper by German authors in Journal of Biological Chemistry, with the common name lyral. Absolutely no guarantee it is the same stuff, as those numbers really make a difference! So, low confidence.

Ref (in case the one below is truncated): http://www.jbc.org/cgi/reprint/273/27/16669.pdf#search="Hydr...
Peer comment(s):

agree Marie-Hélène Hayles : yes - I was just about to post along the same lines, having found similar links by googling. It seems the most likely possibility although the asker woud be advised to contact the client.
11 mins
agree Will Matter : Looks very possible but would agree with MHH that it might be best to contact the client.
17 mins
agree Nesrin : Hydroxymethylpentylcyclohexenecarboxaldehyde in English (carboxal instead of carboxyl) - brings up 130 Google hits.
34 mins
agree Charlesp
9 hrs
agree Veronica Prpic Uhing
10 hrs
disagree ysun : Sorry, but I don't think "carboxyldehyde" is a correct term.//Let me tell you cyclohexene doesn't even have a position 10. An error is an error no matter...
14 hrs
If Journal of Biological Chemistry accepts it... //Indeed it is
Something went wrong...
+2
1 hr

carboxyaldehyde/carboxaldehyde

I don't think a "carboxyldehyd" group exists :) Most likely a typo.

The rest of the name is OK.

4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde

Hydroxyisohexyl-3-cyclohexene carboxaldehyde

HMPCC

CAS no: 31906-04-4

Apparently commercial quality material often contains 2 isomers, that's why the group positions are left unnumbered in your example.

I believe you can write it as a single word os split groups into separate words in English, I've seen both but I'm not familiar with the official conventions.

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Note added at 1 hr (2006-09-06 18:41:15 GMT)
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Looks like I am mostly repeating information given by David and Nesrin. The unique information I can give is that I don't think you need to contact the client :)
Peer comment(s):

agree ysun
1 hr
thank you
agree Veronica Prpic Uhing
8 hrs
thank you
Something went wrong...
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